Ijraset Journal For Research in Applied Science and Engineering Technology
Authors: Shivam Pal, Akshit Srivastav, Ankit Maurya , Devang Yadav, Abhishek Yadav
DOI Link: https://doi.org/10.22214/ijraset.2022.43454
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The ??n?erns ?n ?lim?te ?h?nge, the high energy ?ri?es ?nd the dwindling ?il reserves ?nd su??lies h?ve ne?essit?ted ? str?ng interest in the rese?r?h ?f ?ltern?tive fuel s?ur?es. Bi?diesel is ?n ?ltern?tive renew?ble fuel th?t h?s g?ined m?ssive ?ttenti?n in re?ent ye?rs. Studies ?n the ?hysi??l ?r??erties ?f bi?diesel h?ve sh?wn th?t it is ??m?letely mis?ible with ?etr?leum diesel. Sin?e the ??mbusti?n ?f bi?diesel emits ??rti?ul?te m?tter ?nd g?ses whi?h is l?wer th?n ?etr?diesel, ??mbusti?n ?f bi?diesel ?nd bi?diesel blends h?ve sh?wn ? signifi??nt redu?ti?n in ??rti?ul?te m?tter ?nd exh?ust emissi?ns. In this review ???er, the use ?f ?ure bi?diesel ?r bi?diesel blends in terms ?f ?erf?rm?n?e ?nd exh?ust emissi?ns h?s been studied in ??m??ris?n t? ?etr?leum diesel miner?l diesel. ??mbusti?n dur?ti?n f?r bi?diesel blends w?s sh?rter th?n miner?l diesel.
I. INTRODUCTION
Depletion ?f fossil fuels ?nd environmental awareness has devel??ed the need t? find alternatives t? diesel fuels which ?l?ys ? m?j?r r?le in the industry ?nd the e??n?my ?f any ??untry. Bi?m?ss ?nd especially veget?ble ?ils ?re seen t? be ?n efficient s?luti?n ?n ?n intern?ti?n?l s??le. This n?n-t?xi? res?ur?e ??uld be ?r?du?ed ?t sm?ll s??le, whi?h ??uld ?r?vide energy in ? de?entr?lized m?nner. The ??rb?n emissi?ns ?r?du?ed during the ??mbusti?n ?f these ?ils ?re the ?nes whi?h w?s fixed by the ?l?nt, theref?re veget?ble ?ils d?n't in?re?se the gl?b?l b?l?n?e ?f ??2. N?w?d?ys gre?t ?r?gress h?s been m?de t? im?r?ve the w?y veget?ble ?ils ?re used. The use ?f veget?ble ?ils in unm?dified engines le?ds t? m?ny ?r?blems in l?ng term us?ge. Three m?j?r dr?wb??ks ?f veget?ble ?ils ?dversely ?ffe?t the ?erf?rm?n?e ?f the engine n?mely high vis??sity, ???r v?l?tility ?nd ??lyuns?tur?ted ?h?r??ter. The high vis??sity ?f veget?ble ?ils im?lies ineffi?ient ?um?ing ?nd s?r?y f?rm?ti?n. Theref?re, ?ir ?nd fuel ?re n?t ??tim?lly mixed ?nd ??mbusti?n is in??m?lete. Furtherm?re, the l?w v?l?tility ?f veget?ble ?ils ?nd their ?bility t? ??lymerize (due t? uns?tur?ti?n) le?d t? l?ts ?f ??rb?n de??sits, inje?t?r ??king ?nd ?ist?n ring sti?king. T? elimin?te these issues, m?ny different ?r??esses were devel??ed t? m?ke these ?ils ?d??t t? m?dern engines. They ?ll?w the veget?ble ?ils t? ?tt?in ?r??erties very ?l?se t? miner?l diesel. These ?r??esses in?lude dire?t use by blending, mi?r?emulsi?n, ?yr?lysis, tr?nsesterifi??ti?n et?.
Tr?nsesterifi??ti?n (?l??h?lysis) is ? ?hemi??lre??ti?n between trigly?erides ?resent in the veget?ble ?ils ?nd ?rim?ry ?l??h?ls in the ?resen?e ?f ? ??t?lyst t? ?r?du?e m?n?esters. The l?ng ?nd br?n?hed-?h?in trigly?eride m?le?ules ?re tr?nsf?rmed int? m?n?esters ?nd gly?erine. Sever?l ex?eriment?l investig?ti?ns h?ve been ??rried ?ut by rese?r?hers ?r?und the w?rld t? ev?lu?te the engine ?erf?rm?n?e ?f different bi?diesel blends. Generally, ? slight ??wer loss, redu?ti?n in t?rque ?nd increased b?si? were ?bserved in the see ?f bi?diesel fuelled engines. ?ltin et all. studied the effe?t ?f sunfl?wer ?il, ??tt?nseed ?il, s?y?be?n ?il ?nd their methyl esters in ? single ?ylinder, f?urstr?ke dire?t inje?ti?n diesel engine. They ?bserved ? slight 3 redu?ti?ns in the t?rque ?nd ??wer ?r?du?ed ?nd in?re?sed b?si? in the ??se ?f bi?diesel fuelled engines. Similar results were re??rted by Kaufman ?nd Ziejewski ?nd ?nt?lin et ?l f?r sunfl?wer methyl ester; ?l?rk et ?l., M?d?n?ld. f?r s?ybe?n esters; ?eters?n et ?l. f?r r??eseed ?il methyl ester et?. ??rr?rett??l. ??rried ?ut investig?ti?ns ?n six ?ylinders dire?t inje?ti?n diesel engine. The in?re?se ?f bi?diesel ?er?ent?ge in the blend inv?lves ? slight de?re?se ?f b?th ??wer ?nd t?rque ?ver the entire s?eed r?nge. In ??rti?ul?r, with ?ure bi?diesel, there w?s ? redu?ti?n by ?b?ut 3% m?ximum ??wer ?nd ?b?ut 5% ?f m?ximum t?rque. M?re?ver, with ?ure bi?diesel, the m?ximum t?rque w?s f?und t? h?ve re??hed ? higher engine s?eed. H?wever, ?l-widy?n et ?l re??rted slightly in?re?sed ??wer ?nd l?wer b?si? f?r w?ste ?il bi?diesel fuelled engines.
R?hm?n ?nd ?h?d?tre re??rted ?ver?ge ?f 6% in?re?sed br?ke ??wer ?ut?ut f?r ? K?r?nj? ?il bi?diesel u? t? 40% blend (B40) ?nd with ? further in?re?se in the bi?diesel ?er?ent?ge in the blend, engine ??wer redu?ed. R?hm?n et ?l.ev?lu?ted the ?erf?rm?n?e ?f bi?diesel blends ?t different ??m?ressi?n r?ti?s ?nd inje?ti?n timings ?f the engine. F?r the s?me ??er?ting ??nditi?ns, the ?erf?rm?n?e ?f the engine w?s redu?ed with ?n in?re?se in bi?diesel ?er?ent?ge in the blend.H?wever, with the in?re?se in ??m?ressi?n r?ti? ?nd ?dv?n?es in inje?ti?n timing, this differen?e w?s redu?ed ?nd the engine ?erf?rm?n?e be??me ??m??r?ble t? diesel. N?bi et ?l. investig?ted the ?erf?rm?n?e ?nd emissi?n ?h?r??teristi?s ?f Neem ?il bi?diesel blends in ? DI engine ?nd re??rted ? redu?ti?n in emissi?ns in?luding sm?ke ?nd ??, while N?x emissi?n w?s in?re?sed with diesel-N?ME blends in ??m??ris?n t? ??nventi?n?l diesel fuel.With EGR 15% N?ME-diesel blend sh?wed better BTE ?nd l?wer N?x in ??m??ris?n t? miner?l diesel.
II. BIODIESEL CHARACTERISTICS
Im??rt?nt ?r??erties ?f Neem ?il bi?diesel blends used in the study ?re ??m??red with miner?l diesel . 7.5% Neem ?il bi?diesel blend is within s?e?ified ?STM limit and compare with 100%pure diesel. but the vis??sity ?f ne?t bi?diesel w?s higher th?n s?e?ified ?STM limit ?f 5 ?ST ?t 40? ?. ??l?rifi? v?lue ?f bi?diesel ?nd blend is l?wer th?n miner?l diesel. The density ?f bi?diesel ?nd blend is ?l?se t? miner?l diesel.
The indicative Properties are as follows:
A. Setup for Experimentation
It w?s used f?r delivering sign?ls ?f ?r?nk ?ngle with ? res?luti?n ?f 0.5° ?r?nk ?ngle. ? TD? m?rker w?s used t? l???te the t?? de?d ?entre ??siti?n in every ?y?le ?f the engine. The sign?ls fr?m the ?h?rge ?m?lifier, TD? F?ur-str?ke, single-?ylinder, ??nst?nt-s?eed, w?ter-???led, dire?t inje?ti?n diesel engine (M?ke: Kirl?sk?r ?il Engines Ltd. Indi?; M?del: DM-10) w?s used t? study the effe?t ?f Neem ?il bi?diesel blends ?n ?erf?rm?n?e ?nd emissi?ns ?f the engine. The det?iled s?e?ifi??ti?ns ?f the engine ?re given in T?ble 2.
The engine ??er?ted ?t ? ??nst?nt s?eed ?f 1500 r?m. The inlet v?lve ??ens 4.5° bef?re TD? ?nd ?l?ses 35.5° ?fter BD?. The exh?ust v?lve ??ens 35.5° bef?re BD? ?nd ?l?ses 4.5° ?fter TD?. The fuel inje?ti?n ?ressure re??mmended by the m?nuf??turer is in the r?nge ?f 200-205 b?rs. This engine ??nsists ?f ? gr?vity-fed fuelling system with ?n effi?ient ???er element filter, f?r?e-feed lubri??ti?n f?r the m?in be?ring, l?rge-end be?rings ?nd ??msh?ft bush; run-thr?ugh ?r therm?-si?h?n ???ling system (Figure 1). ? ?iez?ele?tri? ?ressure tr?nsdu?er (M?ke: Kistler Instruments, Switzerl?nd; M?del: 6613?Q09-01) w?s inst?lled in the engine ?ylinder he?d t? ??quire the ??mbusti?n ?ressure–?r?nk ?ngle hist?ry. M??hining f?r inst?ll?ti?n ?f the ?ressure tr?nsdu?er w?s d?ne in the ?ylinder he?d ?nd the engine m?in sh?ft w?s ??u?led with ? ?re?isi?n sh?ft en??der (M?ke: En??der Indi? Limited, F?rid?b?d). Sign?ls fr?m the ?ressure tr?nsdu?er were ?m?lified using ? ?h?rge ?m?lifier. The high-?re?isi?n sh?ft en??der m?rker ?nd sh?ft en??der were ??quired using ? high-s?eed d?t? ??quisiti?n system (M?ke: Hi-Te?hniques, US?; M?del: N?SD?Q). Engine tests ?re d?ne ?t 1500±3 R?M, f?r 200 b?r fuel inje?t?r ?ressure f?r diesel, 100% Neem ?il bi?diesel (NB100) ?nd 20% blend ?f Neem ?il bi?diesel with miner?l diesel (NB20)
The ?ylinder ?ressure d?t? were ??quired f?r 50 ??nse?utive ?y?les ?nd then ?ver?ged t? elimin?te the effe?t ?f ?y?le-t?-?y?le v?ri?ti?ns. ?ll tests were ??rried ?ut ?fter the therm?l st?biliz?ti?n ?f the engine. Exh?ust g?s ????ity w?s me?sured using ? sm?ke ????imeter (M?ke: ?VL ?ustri?, M?del: 437). The exh?ust g?s ??m??siti?n w?s me?sured using ?n exh?ust g?s ?n?lyzer (M?ke: ?VL Indi?, M?del: DIG?S 444).It me?sures ??2, ??, H?, N? ?nd ?2??n?entr?ti?ns in the exh?ust g?s. Ex?eriments were ??ndu?ted ?t 200 b?rs ?f fuel inje?ti?n ?ressure t? ??m??re the ?erf?rm?n?e ?f 20% ?nd 100% bi?diesel blends with miner?l diesel. BSF? f?r NB100 ?nd NB 20 is higher th?n miner?l diesel (Figure 2(?)). BSF? w?s ?bserved t? be in?re?sed with the in?re?sing ?r???rti?n ?f bi?diesel in the fuel. The Br?ke therm?l effi?ien?y ?f ?ure bi?diesel w?s highest ?m?ng the fuels used. ?ll the blends sh?wed higher therm?l effi?ien?y th?n miner?l diesel (Figure 2(b)). Exh?ust g?s tem?er?ture f?r bi?diesel blends is l?wer th?n miner?l diesel (Figure 2(?)). But de?ressi?n in exh?ust g?s tem?er?ture is n?t ?r???rti?n?l t? the qu?ntity ?f bi?diesel in the fuel. L?wer exh?ust g?s tem?er?ture is ??used by better therm?l effi?ien?y.
III. ENGINE EMISSIONS
The emissi?ns ?f ?? in?re?se with in?re?sing l??d (Figure 3 (?)). Higher the l??d, ri?her fuel-?ir mixture is burned, ?nd thus m?re ?? is ?r?du?ed due t? l??k ?f ?xygen. ?t l?wer l??ds, ?? emissi?ns f?r bi?diesel blends ?re ?l?se t? miner?l diesel. ?t higher l??d, the bi?diesel blends sh?w ? signifi??nt redu?ti?n in ?? emissi?n. ?ll the bi?diesel blends exhibit l?wer H? emissi?ns ??m??red t? miner?l diesel (Figure 3(b)). This m?y be due t? better ??mbusti?n ?f bi?diesel blends due t? the ?resen?e ?f ?xygen. ?n in?re?se in the emissi?n ?f N? w?s ?bserved in ??m??ris?n with miner?l diesel f?r the bi?diesel fueled engines (Figure 3(?)). The sm?ke ????ity f?r bi?diesel blend fueled engines w?s l?wer th?n miner?l diesel ?t ?ll l??ds (Figure 3(d)).
IV. COMBUSTION ON CHARACTERSTICS
A. In-cylinder Pressure vs. Crank Angle Diagram
The v?ri?ti?ns in the in-?ylinder ?ressure with the ?r?nk ?ngle f?r 7.5% bio-diesel ?nd 100% purediesel blends ?t different engine ??er?ting ??nditi?ns with ? b?seline d?t? ?f miner?l diesel ?re sh?wn in figures 4(?)-(?). Fr?m these figures, it ??n be n?ti?ed th?t ?t higher engine l??ds, ?ressure trends ?re ?lm?st simil?r f?r ?ll the fuels. 7.5%bi?diesel blend sh?ws del?yed ?ressure rise w.r.t. miner?l diesel ?t l?wer l??ds. F?r 100% purediesel st?rt ?f ?ressure rise is ??m??r?ble with miner?l diesel. t ?ll engine l??ds, ??mbusti?n st?rts e?rlier f?r 100% purediesel th?n miner?l diesel while f?r 7.5% bi?diesel blend, the st?rt ?f ??mbusti?n is del?yed w.r.t. t? miner?l diesel. Igniti?n del?y f?r ?ll fuels de?re?ses ?s the engine l??d in?re?ses be??use the g?s tem?er?ture inside the ?ylinder is higher ?t high engine l??ds, thus redu?es the ?hysi??l igniti?n del?y. The st?rt ?f ??mbusti?n refle?ts the v?ri?ti?n in igniti?n del?y be??use fuel ?um? ?nd inje?t?r settings were ke?t identi??l f?r ?ll fuels. Figure 5(?) sh?ws the m?ximum ?ylinder ?ressure ?t different l??ds f?r different blends. It sh?ws th?t, ?t ?ll engine l??ds, the ?e?k ?ressure f?r the 7.5% bi?diesel blend is higher th?n miner?l diesel. The ?e?k ?ressure f?r 2% bi?diesel is higher be??use ?f the sh?rter igniti?n del?y ?nd f?st burning ?f ???umul?ted fuel. Figure 5(b) sh?ws the ?r?nk ?ngle, ?t whi?h the ?e?k ?ylinder ?ressure is ?tt?ined f?r ?ll fuels under different engine ??er?ting ??nditi?ns. It ??n be ?bserved th?t with in?re?sing engine l??d, ?e?k ?ylinder ?ressure shifts ?w?y fr?m TD? (Figure 5(b)).
Figure 6(?) sh?ws the ?r?nk ?ngle f?r the 5 ?er?ent m?ss fr??ti?n burned. This figure sh?ws th?t 5 ?er ?ent ?f fuel burns e?rlier f?r 100% bi?diesel. This is due t? the e?rlier st?rt ?f ??mbusti?n f?r bi?diesel, ?s suggested e?rlier. 7.5% bi?diesel blend sh?ws del?yed st?rt ?f ??mbusti?n w.r.t. t? miner?l diesel whi?h indi??tes del?y in the st?rt ?f ??mbusti?n due t? higher vis??sity ?f bi?diesel. F?r 100% bi?diesel del?y due t? higher vis??sity is ??m?ens?ted by ? higher ?et?ne number ?f bi?diesel.
Figure 6(b) sh?ws the ?r?nk ?ngle degree f?r 50 ?er ?ent m?ss fr??ti?n burned ?t different engine l??d ??nditi?ns. Bi?diesel blends t?ke less time f?r 50% ??mbusti?n ?s ??m??red t? miner?l diesel. Figure 6(?) sh?ws the ?r?nk ?ngle degree f?r 90 ?er ?ent m?ss fr??ti?n burned ?t different engine l??d ??nditi?ns. Bi?diesel blends t?ke less time f?r 90% ??mbusti?n ?s ??m??red t? miner?l diesel.
Neem oil biodiesels ?nd its blends were ?h?r??terized by me?suring its density, vis??sity ?nd ??l?rifi? v?lue. ?erf?rm?n?e emissi?n ?nd ??mbusti?n ?h?r??teristi?s ?f this bi?diesel ?nd its blends were me?sured in ? ??nst?nt s?eed dire?t inje?ti?n engine. Br?ke specific fuel ??nsum?ti?n f?r bi?diesel ?nd its blends w?s higher th?n miner?l diesel but br?ke therm?l effi?ien?y ?f ?ll the bi?diesel blends w?s l?wer th?n miner?l diesel. Br?ke s?e?ifi? ??2, ?? ?nd Hydr???rb?n emissi?ns f?r bi?diesel fuelled engine ??er?ti?n were l?wer th?n miner?l diesel but N? emissi?ns were higher f?r bi?diesel blends. ??mbusti?n 12 st?rted e?rlier f?r higher bi?diesel blend fuelled ??er?ting ??nditi?ns but the st?rt ?f ??mbusti?n w?s slightly del?yed f?r l?wer blends ?f bi?diesel in ??m??ris?n with miner?l diesel. ??mbusti?n dur?ti?n f?r bi?diesel blends w?s sh?rter th?n miner?l diesel. Blends of NEEM OIL and diesel have a potential to substitute the conventional fuel but with some advantage there is also some disadvantage that we discussed below. These blends can be used in a diesel engine without any modification. Mechanical efficiency at CR 18 increase terrifically with increasing load for sample 2 and sample 3. It is also noticed that mechanical efficiency more increase for sample 3 that is 7.5% of NEEM OIL CR 18 mechanical efficiency decrease with increasing A. Neem Oil BTE remains almost constant or little bit decrease with increase load for sample 2 and sample 3 as compared to sample 1. Initially fuel consumption is low for sample 2 and sample 3 as compared to sample 1 but after increasing load specific fuel consumption remains same for all sample. Overall we can say that less fuel consumption for sample 2 and sample 3 by diesel engine as compared to sample 1 that is pure diesel. Almost same brake mean effective pressure for all sample but at CR 18 notable increase in pressure for sample 3 and sample 2 as compared to sample 1 with increasing load. Nearly same brake power for all CR, only little bit deflection are noticed. For CR 18 higher torque is available for sample 3 10% biodiesel and sample 2 as compared to sample 1 but for in CR 18 7.5% is little bit high torque for sample 1 pure diesel as compared to others. B. Emission Conclusion The CO emission is minimum for all samples at CR 18 as compared to other sample of other CR so it is best suitable for CR 18. But if we compared sample wise CO emission goes minimum at CR 18 for sample 3 as compared to other samples. All sample emission is minimum at CR18 but for SAMPLE 2 at CR 18 initial emission is much minimum as compared to other then gradually increase There is very less NOx emission for sample 2 7.5% biodiesel and Sample 2 at CR 18 as compared to any other sample of any CR. HC Emission is minimum for sample 1 pure diesel at CR18 and CR 18 and maximum HC emission for sample 3 at CR 18.
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Copyright © 2022 Shivam Pal, Akshit Srivastav, Ankit Maurya , Devang Yadav, Abhishek Yadav . This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Paper Id : IJRASET43454
Publish Date : 2022-05-28
ISSN : 2321-9653
Publisher Name : IJRASET
DOI Link : Click Here